Source Name	Characteristics[organism]	Characteristics[taxonomy_id]	Characteristics[biological_replicate]	Characteristics[cultivar]	Characteristics[tissue]	Characteristics[treatment]	Comment[BioSample]	Comment[sample_title]	Protocol REF	Sample Name	Protocol REF	Parameter Value[Post extraction]	Parameter Value[Derivatization]	Extract Name	Protocol REF	Parameter Value[Chromatography instrument]	Parameter Value[Autosampler model]	Parameter Value[Column model]	Parameter Value[Column type]	Parameter Value[Guard column]	Parameter Value[Detector]	Parameter Value[Signal range]	Parameter Value[Resolution]	Labeled Extract Name	Label	Protocol REF	Parameter Value[Scan polarity]	Parameter Value[Scan m/z range]	Parameter Value[Instrument]	Parameter Value[Ion source]	Parameter Value[Mass analyzer]	Assay Name	Comment[technical_replicate]	Raw Data File	Raw Data File	Protocol REF	Processed Data File	Protocol REF	Metabolite Assignment File	Comment[maf_value_unit]	Factor Value[treatment]
Brassica oleracea var. capitata YR Seisyun Leaf	Brassica oleracea var. capitata	3716	1	YR Seisyun	leaf	0t compost	SAMD00519809	Brassica oleracea var. capitata YR Seisyun Leaf S01-1	Sample collection 1	S01-1	Extraction	20 microL sample is injected into HPLC after 0.2 micrometre membrane filter treatment.		S01-1	Chromatography	Agilent 1100 HPLC (Agilent Technologies)		TSKgel ODS-100V (4.6 x 250 mm, 5 micrometre; TOSOH)	reverse phase			200-650 nm	2 nm			Mass spectrometry	positive	100.0-1500.0	LTQ-FT (Thermo Fisher Scientific)	ESI	FT-ICR	S01-1_M01		raw/MDLC1_29142.RAW	raw/MDLC1_29142.mzXML	Data processing		Metabolite identification			0t compost
Brassica oleracea var. capitata YR Seisyun Leaf	Brassica oleracea var. capitata	3716	2	YR Seisyun	leaf	0t compost	SAMD00519810	Brassica oleracea var. capitata YR Seisyun Leaf S01-2	Sample collection 1	S01-2	Extraction	20 microL sample is injected into HPLC after 0.2 micrometre membrane filter treatment.		S01-2	Chromatography	Agilent 1100 HPLC (Agilent Technologies)		TSKgel ODS-100V (4.6 x 250 mm, 5 micrometre; TOSOH)	reverse phase			200-650 nm	2 nm			Mass spectrometry	positive	100.0-1500.0	LTQ-FT (Thermo Fisher Scientific)	ESI	FT-ICR	S01-2_M01		raw/MDLC1_29143.RAW	raw/MDLC1_29143.mzXML	Data processing		Metabolite identification			0t compost
Brassica oleracea var. capitata YR Seisyun Leaf	Brassica oleracea var. capitata	3716	3	YR Seisyun	leaf	0t compost	SAMD00519811	Brassica oleracea var. capitata YR Seisyun Leaf S01-3	Sample collection 1	S01-3	Extraction	20 microL sample is injected into HPLC after 0.2 micrometre membrane filter treatment.		S01-3	Chromatography	Agilent 1100 HPLC (Agilent Technologies)		TSKgel ODS-100V (4.6 x 250 mm, 5 micrometre; TOSOH)	reverse phase			200-650 nm	2 nm			Mass spectrometry	positive	100.0-1500.0	LTQ-FT (Thermo Fisher Scientific)	ESI	FT-ICR	S01-3_M01		raw/MDLC1_29144.RAW	raw/MDLC1_29144.mzXML	Data processing		Metabolite identification			0t compost
Brassica oleracea var. capitata YR Seisyun Leaf, using compost	Brassica oleracea var. capitata	3716	1	YR Seisyun	leaf	6t compost	SAMD00519812	Brassica oleracea var. capitata YR Seisyun Leaf, using compost S02-1	Sample collection 2	S02-1	Extraction	20 microL sample is injected into HPLC after 0.2 micrometre membrane filter treatment.		S02-1	Chromatography	Agilent 1100 HPLC (Agilent Technologies)		TSKgel ODS-100V (4.6 x 250 mm, 5 micrometre; TOSOH)	reverse phase			200-650 nm	2 nm			Mass spectrometry	positive	100.0-1500.0	LTQ-FT (Thermo Fisher Scientific)	ESI	FT-ICR	S02-1_M01		raw/MDLC1_29147.RAW	raw/MDLC1_29147.mzXML	Data processing		Metabolite identification			6t compost
Brassica oleracea var. capitata YR Seisyun Leaf, using compost	Brassica oleracea var. capitata	3716	2	YR Seisyun	leaf	6t compost	SAMD00519813	Brassica oleracea var. capitata YR Seisyun Leaf, using compost S02-2	Sample collection 2	S02-2	Extraction	20 microL sample is injected into HPLC after 0.2 micrometre membrane filter treatment.		S02-2	Chromatography	Agilent 1100 HPLC (Agilent Technologies)		TSKgel ODS-100V (4.6 x 250 mm, 5 micrometre; TOSOH)	reverse phase			200-650 nm	2 nm			Mass spectrometry	positive	100.0-1500.0	LTQ-FT (Thermo Fisher Scientific)	ESI	FT-ICR	S02-2_M01		raw/MDLC1_29148.RAW	raw/MDLC1_29148.mzXML	Data processing		Metabolite identification			6t compost
Brassica oleracea var. capitata YR Seisyun Leaf, using compost	Brassica oleracea var. capitata	3716	3	YR Seisyun	leaf	6t compost	SAMD00519814	Brassica oleracea var. capitata YR Seisyun Leaf, using compost S02-3	Sample collection 2	S02-3	Extraction	20 microL sample is injected into HPLC after 0.2 micrometre membrane filter treatment.		S02-3	Chromatography	Agilent 1100 HPLC (Agilent Technologies)		TSKgel ODS-100V (4.6 x 250 mm, 5 micrometre; TOSOH)	reverse phase			200-650 nm	2 nm			Mass spectrometry	positive	100.0-1500.0	LTQ-FT (Thermo Fisher Scientific)	ESI	FT-ICR	S02-3_M01		raw/MDLC1_29149.RAW	raw/MDLC1_29149.mzXML	Data processing		Metabolite identification			6t compost