data_9LF
#

_chem_comp.id                                   9LF
_chem_comp.name                                 "(2S,12E,14E,16S,17S,18R,19R,20R,21S,22R,23S,24E)-21-(acetyloxy)-5,6,17,19-tetrahydroxy-23-methoxy-2,4,12,16,18,20,22-heptamethyl-1,11-dioxo-1,2-dihydro-2,7-(epoxypentadeca[1,11,13]trienoimino)naphtho[2,1-b]furan-9-yl hydroxyacetate"
_chem_comp.type                                 NON-POLYMER
_chem_comp.pdbx_type                            HETAIN
_chem_comp.formula                              "C39 H49 N O14"
_chem_comp.mon_nstd_parent_comp_id              ?
_chem_comp.pdbx_synonyms                        "Rifamycin L"
_chem_comp.pdbx_formal_charge                   0
_chem_comp.pdbx_initial_date                    2018-05-24
_chem_comp.pdbx_modified_date                   2021-03-01
_chem_comp.pdbx_ambiguous_flag                  N
_chem_comp.pdbx_release_status                  REL
_chem_comp.pdbx_replaced_by                     ?
_chem_comp.pdbx_replaces                        ?
_chem_comp.formula_weight                       755.805
_chem_comp.one_letter_code                      ?
_chem_comp.three_letter_code                    ?
_chem_comp.pdbx_model_coordinates_details       ?
_chem_comp.pdbx_model_coordinates_missing_flag  N
_chem_comp.pdbx_ideal_coordinates_details       Corina
_chem_comp.pdbx_ideal_coordinates_missing_flag  N
_chem_comp.pdbx_model_coordinates_db_code       5YSW
_chem_comp.pdbx_subcomponent_list               ?
_chem_comp.pdbx_processing_site                 PDBJ
#   #
loop_
_chem_comp_atom.comp_id
_chem_comp_atom.atom_id
_chem_comp_atom.alt_atom_id
_chem_comp_atom.type_symbol
_chem_comp_atom.charge
_chem_comp_atom.pdbx_align
_chem_comp_atom.pdbx_aromatic_flag
_chem_comp_atom.pdbx_leaving_atom_flag
_chem_comp_atom.pdbx_stereo_config
_chem_comp_atom.model_Cartn_x
_chem_comp_atom.model_Cartn_y
_chem_comp_atom.model_Cartn_z
_chem_comp_atom.pdbx_model_Cartn_x_ideal
_chem_comp_atom.pdbx_model_Cartn_y_ideal
_chem_comp_atom.pdbx_model_Cartn_z_ideal
_chem_comp_atom.pdbx_component_atom_id
_chem_comp_atom.pdbx_component_comp_id
_chem_comp_atom.pdbx_ordinal
9LF  C01  C1   C  0  1  N  N  N   96.974  60.933  271.251   96.974  60.933  271.251  C01  9LF    1  
9LF  O02  O1   O  0  1  N  N  N   97.009  61.165  272.636   97.009  61.165  272.636  O02  9LF    2  
9LF  C03  C2   C  0  1  N  N  S   96.408  62.356  273.081   96.408  62.356  273.081  C03  9LF    3  
9LF  C04  C3   C  0  1  N  N  N   94.863  62.341  272.912   94.863  62.341  272.912  C04  9LF    4  
9LF  C05  C4   C  0  1  N  N  N   94.080  63.153  273.696   94.080  63.153  273.696  C05  9LF    5  
9LF  O06  O2   O  0  1  N  N  N   92.647  63.169  273.637   92.647  63.169  273.637  O06  9LF    6  
9LF  C07  C5   C  0  1  N  N  S   92.004  63.957  272.600   92.004  63.957  272.600  C07  9LF    7  
9LF  C08  C6   C  0  1  N  N  N   90.546  63.592  272.470   90.546  63.592  272.470  C08  9LF    8  
9LF  O09  O3   O  0  1  N  N  N   92.042  65.378  273.016   92.042  65.378  273.016  O09  9LF    9  
9LF  C10  C7   C  0  1  Y  N  N   93.312  65.891  272.292   93.312  65.891  272.292  C10  9LF   10  
9LF  C11  C8   C  0  1  Y  N  N   94.090  67.018  272.545   94.090  67.018  272.545  C11  9LF   11  
9LF  C12  C9   C  0  1  N  N  N   93.670  67.901  273.675   93.670  67.901  273.675  C12  9LF   12  
9LF  C13  C10  C  0  1  Y  N  N   95.207  67.296  271.785   95.207  67.296  271.785  C13  9LF   13  
9LF  O14  O4   O  0  1  N  N  N   96.022  68.431  271.999   96.022  68.431  271.999  O14  9LF   14  
9LF  C15  C11  C  0  1  Y  N  N   95.530  66.377  270.733   95.530  66.377  270.733  C15  9LF   15  
9LF  C16  C12  C  0  1  Y  N  N   96.660  66.726  269.998   96.660  66.726  269.998  C16  9LF   16  
9LF  O17  O5   O  0  1  N  N  N   97.396  67.897  270.308   97.396  67.897  270.308  O17  9LF   17  
9LF  C18  C13  C  0  1  Y  N  N   97.072  65.897  268.961   97.072  65.897  268.961  C18  9LF   18  
9LF  C19  C14  C  0  1  Y  N  N   96.349  64.721  268.632   96.349  64.721  268.632  C19  9LF   19  
9LF  C20  C15  C  0  1  Y  N  N   95.195  64.368  269.366   95.195  64.368  269.366  C20  9LF   20  
9LF  O21  O6   O  0  1  N  N  N   94.450  63.188  269.034   94.450  63.188  269.034  O21  9LF   21  
9LF  C22  C16  C  0  1  N  N  N   93.415  63.320  268.022   93.415  63.320  268.022  C22  9LF   22  
9LF  O23  O7   O  0  1  N  N  N   92.501  64.061  268.154   92.501  64.061  268.154  O23  9LF   23  
9LF  C24  C17  C  0  1  N  N  N   93.416  62.501  266.709   93.416  62.501  266.709  C24  9LF   24  
9LF  O25  O8   O  0  1  N  N  N   92.809  63.283  265.709   92.809  63.283  265.709  O25  9LF   25  
9LF  C26  C18  C  0  1  Y  N  N   94.786  65.230  270.455   94.786  65.230  270.455  C26  9LF   26  
9LF  C27  C19  C  0  1  Y  N  N   93.629  64.971  271.243   93.629  64.971  271.243  C27  9LF   27  
9LF  C28  C20  C  0  1  N  N  N   92.641  63.944  271.336   92.641  63.944  271.336  C28  9LF   28  
9LF  O29  O9   O  0  1  N  N  N   92.374  63.136  270.514   92.374  63.136  270.514  O29  9LF   29  
9LF  N30  N1   N  0  1  N  N  N   98.274  66.387  268.285   98.274  66.387  268.285  N30  9LF   30  
9LF  C31  C21  C  0  1  N  N  N   99.646  65.953  268.576   99.646  65.953  268.576  C31  9LF   31  
9LF  O32  O10  O  0  1  N  N  N  100.507  66.471  267.945  100.507  66.471  267.945  O32  9LF   32  
9LF  C33  C22  C  0  1  N  N  N  100.016  64.828  269.595  100.016  64.828  269.595  C33  9LF   33  
9LF  C34  C23  C  0  1  N  N  N  101.430  64.299  269.504  101.430  64.299  269.504  C34  9LF   34  
9LF  C35  C24  C  0  1  N  N  N   99.194  64.322  270.537   99.194  64.322  270.537  C35  9LF   35  
9LF  C36  C25  C  0  1  N  N  N   99.707  63.159  271.472   99.707  63.159  271.472  C36  9LF   36  
9LF  C37  C26  C  0  1  N  N  N  100.999  63.122  271.910  100.999  63.122  271.910  C37  9LF   37  
9LF  C38  C27  C  0  1  N  N  S  101.717  62.081  272.783  101.717  62.081  272.783  C38  9LF   38  
9LF  C39  C28  C  0  1  N  N  N  101.449  60.649  272.332  101.449  60.649  272.332  C39  9LF   39  
9LF  C40  C29  C  0  1  N  N  S  101.413  62.392  274.274  101.413  62.392  274.274  C40  9LF   40  
9LF  O41  O11  O  0  1  N  N  N  102.490  63.108  274.750  102.490  63.108  274.750  O41  9LF   41  
9LF  C42  C30  C  0  1  N  N  R  101.231  61.163  275.162  101.231  61.163  275.162  C42  9LF   42  
9LF  C43  C31  C  0  1  N  N  N  101.096  61.637  276.593  101.096  61.637  276.593  C43  9LF   43  
9LF  C44  C32  C  0  1  N  N  R   99.976  60.351  274.776   99.976  60.351  274.776  C44  9LF   44  
9LF  O45  O12  O  0  1  N  N  N  100.122  59.101  275.367  100.122  59.101  275.367  O45  9LF   45  
9LF  C46  C33  C  0  1  N  N  R   98.598  60.912  275.216   98.598  60.912  275.216  C46  9LF   46  
9LF  C47  C34  C  0  1  N  N  N   98.357  60.700  276.722   98.357  60.700  276.722  C47  9LF   47  
9LF  C48  C35  C  0  1  N  N  S   98.255  62.364  274.749   98.255  62.364  274.749  C48  9LF   48  
9LF  O49  O13  O  0  1  N  N  N   98.735  63.407  275.576   98.735  63.407  275.576  O49  9LF   49  
9LF  C50  C36  C  0  1  N  N  N   98.359  64.750  275.247   98.359  64.750  275.247  C50  9LF   50  
9LF  C51  C37  C  0  1  N  N  N   97.509  65.559  276.232   97.509  65.559  276.232  C51  9LF   51  
9LF  O52  O14  O  0  1  N  N  N   98.698  65.261  274.227   98.698  65.261  274.227  O52  9LF   52  
9LF  C53  C38  C  0  1  N  N  R   96.730  62.521  274.575   96.730  62.521  274.575  C53  9LF   53  
9LF  C54  C39  C  0  1  N  N  N   95.905  61.576  275.466   95.905  61.576  275.466  C54  9LF   54  
9LF  H1   H1   H  0  1  N  N  N   97.471  59.978  271.026   97.471  59.978  271.026  H1   9LF   55  
9LF  H2   H2   H  0  1  N  N  N   95.928  60.890  270.913   95.928  60.890  270.913  H2   9LF   56  
9LF  H3   H3   H  0  1  N  N  N   97.495  61.749  270.729   97.495  61.749  270.729  H3   9LF   57  
9LF  H4   H4   H  0  1  N  N  N   96.812  63.221  272.534   96.812  63.221  272.534  H4   9LF   58  
9LF  H5   H5   H  0  1  N  N  N   94.406  61.693  272.179   94.406  61.693  272.179  H5   9LF   59  
9LF  H6   H6   H  0  1  N  N  N   94.570  63.815  274.395   94.570  63.815  274.395  H6   9LF   60  
9LF  H7   H7   H  0  1  N  N  N   90.073  63.609  273.463   90.073  63.609  273.463  H7   9LF   61  
9LF  H8   H8   H  0  1  N  N  N   90.044  64.317  271.813   90.044  64.317  271.813  H8   9LF   62  
9LF  H9   H9   H  0  1  N  N  N   90.458  62.584  272.039   90.458  62.584  272.039  H9   9LF   63  
9LF  H10  H10  H  0  1  N  N  N   92.981  68.673  273.301   92.981  68.673  273.301  H10  9LF   64  
9LF  H11  H11  H  0  1  N  N  N   93.163  67.298  274.443   93.163  67.298  274.443  H11  9LF   65  
9LF  H12  H12  H  0  1  N  N  N   94.557  68.382  274.113   94.557  68.382  274.113  H12  9LF   66  
9LF  H13  H13  H  0  1  N  N  N   95.678  68.936  272.726   95.678  68.936  272.726  H13  9LF   67  
9LF  H14  H14  H  0  1  N  N  N   96.984  68.347  271.036   96.984  68.347  271.036  H14  9LF   68  
9LF  H15  H15  H  0  1  N  N  N   96.682  64.094  267.818   96.682  64.094  267.818  H15  9LF   69  
9LF  H16  H16  H  0  1  N  N  N   92.849  61.569  266.850   92.849  61.569  266.850  H16  9LF   70  
9LF  H17  H17  H  0  1  N  N  N   94.450  62.261  266.419   94.450  62.261  266.419  H17  9LF   71  
9LF  H18  H18  H  0  1  N  N  N   92.356  64.015  266.110   92.356  64.015  266.110  H18  9LF   72  
9LF  H19  H19  H  0  1  N  N  N   98.151  67.072  267.567   98.151  67.072  267.567  H19  9LF   73  
9LF  H20  H20  H  0  1  N  N  N  101.579  63.517  270.263  101.579  63.516  270.263  H20  9LF   74  
9LF  H21  H21  H  0  1  N  N  N  101.599  63.876  268.503  101.599  63.876  268.503  H21  9LF   75  
9LF  H22  H22  H  0  1  N  N  N  102.141  65.120  269.680  102.141  65.120  269.680  H22  9LF   76  
9LF  H23  H23  H  0  1  N  N  N   98.192  64.710  270.650   98.192  64.710  270.651  H23  9LF   77  
9LF  H24  H24  H  0  1  N  N  N   99.023  62.378  271.771   99.023  62.378  271.771  H24  9LF   78  
9LF  H25  H25  H  0  1  N  N  N  101.612  63.953  271.594  101.612  63.953  271.594  H25  9LF   79  
9LF  H26  H26  H  0  1  N  N  N  102.795  62.254  272.648  102.795  62.254  272.648  H26  9LF   80  
9LF  H27  H27  H  0  1  N  N  N  101.986  59.950  272.990  101.986  59.950  272.990  H27  9LF   81  
9LF  H28  H28  H  0  1  N  N  N  100.369  60.445  272.383  100.369  60.445  272.383  H28  9LF   82  
9LF  H29  H29  H  0  1  N  N  N  101.798  60.519  271.297  101.798  60.519  271.297  H29  9LF   83  
9LF  H30  H30  H  0  1  N  N  N  100.495  62.996  274.319  100.495  62.996  274.319  H30  9LF   84  
9LF  H31  H31  H  0  1  N  N  N  102.349  63.323  275.665  102.349  63.323  275.665  H31  9LF   85  
9LF  H32  H32  H  0  1  N  N  N  102.117  60.517  275.073  102.117  60.517  275.073  H32  9LF   86  
9LF  H33  H33  H  0  1  N  N  N  100.963  60.769  277.256  100.963  60.770  277.256  H33  9LF   87  
9LF  H34  H34  H  0  1  N  N  N  102.004  62.186  276.884  102.004  62.186  276.884  H34  9LF   88  
9LF  H35  H35  H  0  1  N  N  N  100.223  62.301  276.678  100.223  62.301  276.678  H35  9LF   89  
9LF  H36  H36  H  0  1  N  N  N   99.963  60.249  273.681   99.963  60.249  273.681  H36  9LF   90  
9LF  H37  H37  H  0  1  N  N  N   99.369  58.561  275.157   99.369  58.561  275.157  H37  9LF   91  
9LF  H38  H38  H  0  1  N  N  N   97.857  60.272  274.714   97.857  60.272  274.715  H38  9LF   92  
9LF  H39  H39  H  0  1  N  N  N   98.614  59.665  276.993   98.614  59.665  276.993  H39  9LF   93  
9LF  H40  H40  H  0  1  N  N  N   98.987  61.396  277.296   98.987  61.396  277.296  H40  9LF   94  
9LF  H41  H41  H  0  1  N  N  N   97.298  60.887  276.954   97.298  60.887  276.954  H41  9LF   95  
9LF  H42  H42  H  0  1  N  N  N   98.701  62.484  273.750   98.701  62.484  273.750  H42  9LF   96  
9LF  H43  H43  H  0  1  N  N  N   97.326  66.563  275.821   97.326  66.563  275.821  H43  9LF   97  
9LF  H44  H44  H  0  1  N  N  N   96.548  65.048  276.393   96.548  65.048  276.393  H44  9LF   98  
9LF  H45  H45  H  0  1  N  N  N   98.042  65.647  277.190   98.043  65.647  277.190  H45  9LF   99  
9LF  H46  H46  H  0  1  N  N  N   96.470  63.552  274.857   96.470  63.552  274.858  H46  9LF  100  
9LF  H47  H47  H  0  1  N  N  N   96.175  61.736  276.520   96.175  61.736  276.520  H47  9LF  101  
9LF  H48  H48  H  0  1  N  N  N   94.834  61.783  275.326   94.834  61.783  275.327  H48  9LF  102  
9LF  H49  H49  H  0  1  N  N  N   96.116  60.533  275.188   96.116  60.533  275.188  H49  9LF  103  
#   #
loop_
_chem_comp_bond.comp_id
_chem_comp_bond.atom_id_1
_chem_comp_bond.atom_id_2
_chem_comp_bond.value_order
_chem_comp_bond.pdbx_aromatic_flag
_chem_comp_bond.pdbx_stereo_config
_chem_comp_bond.pdbx_ordinal
9LF  O25  C24  SING  N  N    1  
9LF  C24  C22  SING  N  N    2  
9LF  O32  C31  DOUB  N  N    3  
9LF  C22  O23  DOUB  N  N    4  
9LF  C22  O21  SING  N  N    5  
9LF  N30  C31  SING  N  N    6  
9LF  N30  C18  SING  N  N    7  
9LF  C31  C33  SING  N  N    8  
9LF  C19  C18  DOUB  Y  N    9  
9LF  C19  C20  SING  Y  N   10  
9LF  C18  C16  SING  Y  N   11  
9LF  O21  C20  SING  N  N   12  
9LF  C20  C26  DOUB  Y  N   13  
9LF  C34  C33  SING  N  N   14  
9LF  C33  C35  DOUB  N  E   15  
9LF  C16  O17  SING  N  N   16  
9LF  C16  C15  DOUB  Y  N   17  
9LF  C26  C15  SING  Y  N   18  
9LF  C26  C27  SING  Y  N   19  
9LF  O29  C28  DOUB  N  N   20  
9LF  C35  C36  SING  N  N   21  
9LF  C15  C13  SING  Y  N   22  
9LF  C27  C28  SING  N  N   23  
9LF  C27  C10  DOUB  Y  N   24  
9LF  C01  O02  SING  N  N   25  
9LF  C28  C07  SING  N  N   26  
9LF  C36  C37  DOUB  N  E   27  
9LF  C13  O14  SING  N  N   28  
9LF  C13  C11  DOUB  Y  N   29  
9LF  C37  C38  SING  N  N   30  
9LF  C10  C11  SING  Y  N   31  
9LF  C10  O09  SING  N  N   32  
9LF  C39  C38  SING  N  N   33  
9LF  C08  C07  SING  N  N   34  
9LF  C11  C12  SING  N  N   35  
9LF  C07  O09  SING  N  N   36  
9LF  C07  O06  SING  N  N   37  
9LF  O02  C03  SING  N  N   38  
9LF  C38  C40  SING  N  N   39  
9LF  C04  C03  SING  N  N   40  
9LF  C04  C05  DOUB  N  E   41  
9LF  C03  C53  SING  N  N   42  
9LF  O06  C05  SING  N  N   43  
9LF  O52  C50  DOUB  N  N   44  
9LF  C40  O41  SING  N  N   45  
9LF  C40  C42  SING  N  N   46  
9LF  C53  C48  SING  N  N   47  
9LF  C53  C54  SING  N  N   48  
9LF  C48  C46  SING  N  N   49  
9LF  C48  O49  SING  N  N   50  
9LF  C44  C42  SING  N  N   51  
9LF  C44  C46  SING  N  N   52  
9LF  C44  O45  SING  N  N   53  
9LF  C42  C43  SING  N  N   54  
9LF  C46  C47  SING  N  N   55  
9LF  C50  O49  SING  N  N   56  
9LF  C50  C51  SING  N  N   57  
9LF  C01  H1   SING  N  N   58  
9LF  C01  H2   SING  N  N   59  
9LF  C01  H3   SING  N  N   60  
9LF  C03  H4   SING  N  N   61  
9LF  C04  H5   SING  N  N   62  
9LF  C05  H6   SING  N  N   63  
9LF  C08  H7   SING  N  N   64  
9LF  C08  H8   SING  N  N   65  
9LF  C08  H9   SING  N  N   66  
9LF  C12  H10  SING  N  N   67  
9LF  C12  H11  SING  N  N   68  
9LF  C12  H12  SING  N  N   69  
9LF  O14  H13  SING  N  N   70  
9LF  O17  H14  SING  N  N   71  
9LF  C19  H15  SING  N  N   72  
9LF  C24  H16  SING  N  N   73  
9LF  C24  H17  SING  N  N   74  
9LF  O25  H18  SING  N  N   75  
9LF  N30  H19  SING  N  N   76  
9LF  C34  H20  SING  N  N   77  
9LF  C34  H21  SING  N  N   78  
9LF  C34  H22  SING  N  N   79  
9LF  C35  H23  SING  N  N   80  
9LF  C36  H24  SING  N  N   81  
9LF  C37  H25  SING  N  N   82  
9LF  C38  H26  SING  N  N   83  
9LF  C39  H27  SING  N  N   84  
9LF  C39  H28  SING  N  N   85  
9LF  C39  H29  SING  N  N   86  
9LF  C40  H30  SING  N  N   87  
9LF  O41  H31  SING  N  N   88  
9LF  C42  H32  SING  N  N   89  
9LF  C43  H33  SING  N  N   90  
9LF  C43  H34  SING  N  N   91  
9LF  C43  H35  SING  N  N   92  
9LF  C44  H36  SING  N  N   93  
9LF  O45  H37  SING  N  N   94  
9LF  C46  H38  SING  N  N   95  
9LF  C47  H39  SING  N  N   96  
9LF  C47  H40  SING  N  N   97  
9LF  C47  H41  SING  N  N   98  
9LF  C48  H42  SING  N  N   99  
9LF  C51  H43  SING  N  N  100  
9LF  C51  H44  SING  N  N  101  
9LF  C51  H45  SING  N  N  102  
9LF  C53  H46  SING  N  N  103  
9LF  C54  H47  SING  N  N  104  
9LF  C54  H48  SING  N  N  105  
9LF  C54  H49  SING  N  N  106  
#   #
loop_
_pdbx_chem_comp_descriptor.comp_id
_pdbx_chem_comp_descriptor.type
_pdbx_chem_comp_descriptor.program
_pdbx_chem_comp_descriptor.program_version
_pdbx_chem_comp_descriptor.descriptor
9LF  SMILES            ACDLabs               12.01  "COC1C(C(C(C(C(C(C(C=CC=C(C(Nc4c(c3c(c(c2OC(OC=C1)(C)C(c2c3c(c4)OC(=O)CO)=O)C)O)O)=O)C)C)O)C)O)C)OC(C)=O)C"  
9LF  InChI             InChI                 1.03   "InChI=1S/C39H49NO14/c1-17-11-10-12-18(2)38(49)40-24-15-26(53-27(43)16-41)28-29(34(24)47)33(46)22(6)36-30(28)37(48)39(8,54-36)51-14-13-25(50-9)19(3)35(52-23(7)42)21(5)32(45)20(4)31(17)44/h10-15,17,19-21,25,31-32,35,41,44-47H,16H2,1-9H3,(H,40,49)/b11-10+,14-13+,18-12+/t17-,19+,20+,21+,25-,31-,32+,35+,39-/m0/s1"  
9LF  InChIKey          InChI                 1.03   OCUBKDJIPNISSD-WPPPCPPGSA-N  
9LF  SMILES_CANONICAL  CACTVS                3.385  "CO[C@H]1\C=C\O[C@@]2(C)Oc3c(C)c(O)c4c(O)c(NC(=O)\C(=C\C=C\[C@H](C)[C@H](O)[C@@H](C)[C@@H](O)[C@@H](C)[C@H](OC(C)=O)[C@@H]1C)C)cc(OC(=O)CO)c4c3C2=O"  
9LF  SMILES            CACTVS                3.385  "CO[CH]1C=CO[C]2(C)Oc3c(C)c(O)c4c(O)c(NC(=O)C(=CC=C[CH](C)[CH](O)[CH](C)[CH](O)[CH](C)[CH](OC(C)=O)[CH]1C)C)cc(OC(=O)CO)c4c3C2=O"  
9LF  SMILES_CANONICAL  "OpenEye OEToolkits"  2.0.6  "Cc1c(c2c3c(cc(c2O)NC(=O)/C(=C/C=C/[C@@H]([C@@H]([C@H]([C@H]([C@H]([C@@H]([C@@H]([C@H](/C=C/O[C@@]4(C(=O)c3c1O4)C)OC)C)OC(=O)C)C)O)C)O)C)/C)OC(=O)CO)O"  
9LF  SMILES            "OpenEye OEToolkits"  2.0.6  "Cc1c(c2c3c(cc(c2O)NC(=O)C(=CC=CC(C(C(C(C(C(C(C(C=COC4(C(=O)c3c1O4)C)OC)C)OC(=O)C)C)O)C)O)C)C)OC(=O)CO)O"  
#   #
loop_
_pdbx_chem_comp_identifier.comp_id
_pdbx_chem_comp_identifier.type
_pdbx_chem_comp_identifier.program
_pdbx_chem_comp_identifier.program_version
_pdbx_chem_comp_identifier.identifier
9LF  "SYSTEMATIC NAME"  ACDLabs               12.01  "(2S,12E,14E,16S,17S,18R,19R,20R,21S,22R,23S,24E)-21-(acetyloxy)-5,6,17,19-tetrahydroxy-23-methoxy-2,4,12,16,18,20,22-heptamethyl-1,11-dioxo-1,2-dihydro-2,7-(epoxypentadeca[1,11,13]trienoimino)naphtho[2,1-b]furan-9-yl hydroxyacetate"  
9LF  "SYSTEMATIC NAME"  "OpenEye OEToolkits"  2.0.6  "[(4~{E},6~{E},8~{S},9~{S},10~{R},11~{R},12~{R},13~{S},14~{R},15~{S},16~{E},19~{S})-13-acetyloxy-15-methoxy-4,8,10,12,14,19,28-heptamethyl-9,11,25,27-tetrakis(oxidanyl)-3,20-bis(oxidanylidene)-18,30-dioxa-2-azatetracyclo[17.6.5.0^{21,29}.0^{22,26}]triaconta-1(24),4,6,16,21(29),22,25,27-octaen-23-yl] 2-oxidanylethanoate"  
#   #
loop_
_pdbx_chem_comp_audit.comp_id
_pdbx_chem_comp_audit.action_type
_pdbx_chem_comp_audit.date
_pdbx_chem_comp_audit.processing_site
9LF  "Create component"  2018-05-24  PDBJ  
9LF  "Modify synonyms"   2018-06-07  PDBJ  
9LF  "Initial release"   2018-07-04  RCSB  
9LF  "Modify synonyms"   2021-03-01  PDBE  
#
_pdbx_chem_comp_synonyms.ordinal     1
_pdbx_chem_comp_synonyms.comp_id     9LF
_pdbx_chem_comp_synonyms.name        "Rifamycin L"
_pdbx_chem_comp_synonyms.provenance  ?
_pdbx_chem_comp_synonyms.type        ?
##
