data_2FJ
#

_chem_comp.id                                   2FJ
_chem_comp.name                                 "tetrakis(2,2'-bipyridine-kappa~2~N~1~,N~1'~)(mu-tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]phenazine-1kappa~2~N~4~,N~5~:2kappa~2~N~13~,N~14~)diruthenium(4+) L enantiomer"
_chem_comp.type                                 NON-POLYMER
_chem_comp.pdbx_type                            HETAIN
_chem_comp.formula                              "C64 H44 N14 Ru2"
_chem_comp.mon_nstd_parent_comp_id              ?
_chem_comp.pdbx_synonyms                        ?
_chem_comp.pdbx_formal_charge                   4
_chem_comp.pdbx_initial_date                    2013-10-08
_chem_comp.pdbx_modified_date                   2013-10-25
_chem_comp.pdbx_ambiguous_flag                  N
_chem_comp.pdbx_release_status                  REL
_chem_comp.pdbx_replaced_by                     ?
_chem_comp.pdbx_replaces                        ?
_chem_comp.formula_weight                       1211.268
_chem_comp.one_letter_code                      ?
_chem_comp.three_letter_code                    2FJ
_chem_comp.pdbx_model_coordinates_details       ?
_chem_comp.pdbx_model_coordinates_missing_flag  N
_chem_comp.pdbx_ideal_coordinates_details       Corina
_chem_comp.pdbx_ideal_coordinates_missing_flag  Y
_chem_comp.pdbx_model_coordinates_db_code       2MCO
_chem_comp.pdbx_subcomponent_list               ?
_chem_comp.pdbx_processing_site                 RCSB
#   #
loop_
_chem_comp_atom.comp_id
_chem_comp_atom.atom_id
_chem_comp_atom.alt_atom_id
_chem_comp_atom.type_symbol
_chem_comp_atom.charge
_chem_comp_atom.pdbx_align
_chem_comp_atom.pdbx_aromatic_flag
_chem_comp_atom.pdbx_leaving_atom_flag
_chem_comp_atom.pdbx_stereo_config
_chem_comp_atom.model_Cartn_x
_chem_comp_atom.model_Cartn_y
_chem_comp_atom.model_Cartn_z
_chem_comp_atom.pdbx_model_Cartn_x_ideal
_chem_comp_atom.pdbx_model_Cartn_y_ideal
_chem_comp_atom.pdbx_model_Cartn_z_ideal
_chem_comp_atom.pdbx_component_atom_id
_chem_comp_atom.pdbx_component_comp_id
_chem_comp_atom.pdbx_ordinal
2FJ  C1   C1   C   0  1  Y  N  N  38.365  25.235  26.017  ?  ?  ?  C1   2FJ    1  
2FJ  N1   N1   N   0  1  Y  N  N  39.425  25.131  26.894  ?  ?  ?  N1   2FJ    2  
2FJ  C2   C2   C   0  1  Y  N  N  37.333  24.290  26.080  ?  ?  ?  C2   2FJ    3  
2FJ  N2   N2   N   0  1  Y  N  N  41.231  25.215  28.831  ?  ?  ?  N2   2FJ    4  
2FJ  C3   C3   C   0  1  Y  N  N  37.425  23.180  26.985  ?  ?  ?  C3   2FJ    5  
2FJ  N3   N3   N   0  1  Y  N  N  40.590  27.569  25.348  ?  ?  ?  N3   2FJ    6  
2FJ  C4   C4   C   0  1  Y  N  N  38.461  23.087  27.839  ?  ?  ?  C4   2FJ    7  
2FJ  N4   N4   N   0  1  Y  N  N  42.251  25.699  25.908  ?  ?  ?  N4   2FJ    8  
2FJ  C5   C5   C   0  1  Y  N  N  39.440  24.087  27.761  ?  ?  ?  C5   2FJ    9  
2FJ  N5   N5   N   0  1  Y  N  N  42.217  28.012  27.775  ?  ?  ?  N5   2FJ   10  
2FJ  C6   C6   C   0  1  Y  N  N  38.530  22.087  28.814  ?  ?  ?  C6   2FJ   11  
2FJ  N6   N6   N   0  1  Y  N  N  39.600  27.831  28.317  ?  ?  ?  N6   2FJ   12  
2FJ  C7   C7   C   0  1  Y  N  N  42.136  25.291  29.839  ?  ?  ?  C7   2FJ   13  
2FJ  N7   N7   N   0  1  Y  N  N  35.537  17.369  31.082  ?  ?  ?  N7   2FJ   14  
2FJ  C8   C8   C   0  1  Y  N  N  42.301  24.255  30.726  ?  ?  ?  C8   2FJ   15  
2FJ  N8   N8   N   0  1  Y  N  N  37.562  21.080  28.764  ?  ?  ?  N8   2FJ   16  
2FJ  C9   C9   C   0  1  Y  N  N  41.521  23.144  30.654  ?  ?  ?  C9   2FJ   17  
2FJ  N9   N9   N   0  1  Y  N  N  37.534  17.206  32.773  ?  ?  ?  N9   2FJ   18  
2FJ  C10  C10  C   0  1  Y  N  N  40.510  23.078  29.698  ?  ?  ?  C10  2FJ   19  
2FJ  N10  N10  N   0  1  Y  N  N  39.643  20.894  30.597  ?  ?  ?  N10  2FJ   20  
2FJ  C11  C11  C   0  1  Y  N  N  40.407  24.157  28.810  ?  ?  ?  C11  2FJ   21  
2FJ  N11  N11  N   0  1  Y  N  N  33.713  15.620  32.667  ?  ?  ?  N11  2FJ   22  
2FJ  C12  C12  C   0  1  Y  N  N  39.638  22.001  29.732  ?  ?  ?  C12  2FJ   23  
2FJ  N12  N12  N   0  1  Y  N  N  34.789  17.754  33.956  ?  ?  ?  N12  2FJ   24  
2FJ  C13  C13  C   0  1  Y  N  N  39.729  28.629  25.121  ?  ?  ?  C13  2FJ   25  
2FJ  N13  N13  N   0  1  Y  N  N  36.490  14.584  31.850  ?  ?  ?  N13  2FJ   26  
2FJ  C14  C14  C   0  1  Y  N  N  39.658  29.393  23.944  ?  ?  ?  C14  2FJ   27  
2FJ  N14  N14  N   0  1  Y  N  N  36.282  14.995  34.427  ?  ?  ?  N14  2FJ   28  
2FJ  C15  C15  C   0  1  Y  N  N  40.673  29.212  22.986  ?  ?  ?  C15  2FJ   29  
2FJ  C16  C16  C   0  1  Y  N  N  41.573  28.121  23.178  ?  ?  ?  C16  2FJ   30  
2FJ  C17  C17  C   0  1  Y  N  N  41.450  27.320  24.347  ?  ?  ?  C17  2FJ   31  
2FJ  C18  C18  C   0  1  Y  N  N  43.169  24.754  26.318  ?  ?  ?  C18  2FJ   32  
2FJ  C19  C19  C   0  1  Y  N  N  44.129  24.236  25.448  ?  ?  ?  C19  2FJ   33  
2FJ  C20  C20  C   0  1  Y  N  N  44.301  24.743  24.216  ?  ?  ?  C20  2FJ   34  
2FJ  C21  C21  C   0  1  Y  N  N  43.557  25.847  23.835  ?  ?  ?  C21  2FJ   35  
2FJ  C22  C22  C   0  1  Y  N  N  42.467  26.216  24.710  ?  ?  ?  C22  2FJ   36  
2FJ  C23  C23  C   0  1  Y  N  N  43.530  28.065  27.427  ?  ?  ?  C23  2FJ   37  
2FJ  C24  C24  C   0  1  Y  N  N  44.330  29.118  27.851  ?  ?  ?  C24  2FJ   38  
2FJ  C25  C25  C   0  1  Y  N  N  43.817  30.271  28.521  ?  ?  ?  C25  2FJ   39  
2FJ  C26  C26  C   0  1  Y  N  N  42.470  30.212  28.846  ?  ?  ?  C26  2FJ   40  
2FJ  C27  C27  C   0  1  Y  N  N  41.690  29.107  28.407  ?  ?  ?  C27  2FJ   41  
2FJ  C28  C28  C   0  1  Y  N  N  38.283  27.612  28.657  ?  ?  ?  C28  2FJ   42  
2FJ  C29  C29  C   0  1  Y  N  N  37.522  28.544  29.424  ?  ?  ?  C29  2FJ   43  
2FJ  C30  C30  C   0  1  Y  N  N  38.211  29.599  30.029  ?  ?  ?  C30  2FJ   44  
2FJ  C31  C31  C   0  1  Y  N  N  39.508  29.876  29.668  ?  ?  ?  C31  2FJ   45  
2FJ  C32  C32  C   0  1  Y  N  N  40.184  28.951  28.822  ?  ?  ?  C32  2FJ   46  
2FJ  C33  C33  C   0  1  Y  N  N  34.442  17.325  30.220  ?  ?  ?  C33  2FJ   47  
2FJ  C34  C34  C   0  1  Y  N  N  34.442  18.181  29.141  ?  ?  ?  C34  2FJ   48  
2FJ  C35  C35  C   0  1  Y  N  N  35.405  19.166  29.011  ?  ?  ?  C35  2FJ   49  
2FJ  C36  C36  C   0  1  Y  N  N  36.592  19.153  29.808  ?  ?  ?  C36  2FJ   50  
2FJ  C37  C37  C   0  1  Y  N  N  36.575  18.180  30.839  ?  ?  ?  C37  2FJ   51  
2FJ  C38  C38  C   0  1  Y  N  N  37.617  20.067  29.649  ?  ?  ?  C38  2FJ   52  
2FJ  C39  C39  C   0  1  Y  N  N  38.510  17.214  33.748  ?  ?  ?  C39  2FJ   53  
2FJ  C40  C40  C   0  1  Y  N  N  39.588  18.082  33.578  ?  ?  ?  C40  2FJ   54  
2FJ  C41  C41  C   0  1  Y  N  N  39.702  19.030  32.534  ?  ?  ?  C41  2FJ   55  
2FJ  C42  C42  C   0  1  Y  N  N  38.740  18.959  31.593  ?  ?  ?  C42  2FJ   56  
2FJ  C43  C43  C   0  1  Y  N  N  37.644  18.088  31.770  ?  ?  ?  C43  2FJ   57  
2FJ  C44  C44  C   0  1  Y  N  N  38.667  20.000  30.577  ?  ?  ?  C44  2FJ   58  
2FJ  C45  C45  C   0  1  Y  N  N  33.243  14.435  32.201  ?  ?  ?  C45  2FJ   59  
2FJ  C46  C46  C   0  1  Y  N  N  31.887  14.020  32.330  ?  ?  ?  C46  2FJ   60  
2FJ  C47  C47  C   0  1  Y  N  N  31.000  14.958  32.896  ?  ?  ?  C47  2FJ   61  
2FJ  C48  C48  C   0  1  Y  N  N  31.396  16.284  33.231  ?  ?  ?  C48  2FJ   62  
2FJ  C49  C49  C   0  1  Y  N  N  32.760  16.542  33.135  ?  ?  ?  C49  2FJ   63  
2FJ  C50  C50  C   0  1  Y  N  N  35.306  18.839  34.586  ?  ?  ?  C50  2FJ   64  
2FJ  C51  C51  C   0  1  Y  N  N  34.556  19.879  35.022  ?  ?  ?  C51  2FJ   65  
2FJ  C52  C52  C   0  1  Y  N  N  33.182  19.848  34.939  ?  ?  ?  C52  2FJ   66  
2FJ  C53  C53  C   0  1  Y  N  N  32.627  18.778  34.236  ?  ?  ?  C53  2FJ   67  
2FJ  C54  C54  C   0  1  Y  N  N  33.428  17.720  33.810  ?  ?  ?  C54  2FJ   68  
2FJ  C55  C55  C   0  1  Y  N  N  36.658  14.415  30.515  ?  ?  ?  C55  2FJ   69  
2FJ  C56  C56  C   0  1  Y  N  N  37.237  13.277  29.944  ?  ?  ?  C56  2FJ   70  
2FJ  C57  C57  C   0  1  Y  N  N  37.583  12.254  30.767  ?  ?  ?  C57  2FJ   71  
2FJ  C58  C58  C   0  1  Y  N  N  37.475  12.292  32.138  ?  ?  ?  C58  2FJ   72  
2FJ  C59  C59  C   0  1  Y  N  N  36.954  13.532  32.645  ?  ?  ?  C59  2FJ   73  
2FJ  C60  C60  C   0  1  Y  N  N  36.008  15.251  35.725  ?  ?  ?  C60  2FJ   74  
2FJ  C61  C61  C   0  1  Y  N  N  36.179  14.331  36.751  ?  ?  ?  C61  2FJ   75  
2FJ  C62  C62  C   0  1  Y  N  N  36.725  13.069  36.450  ?  ?  ?  C62  2FJ   76  
2FJ  C63  C63  C   0  1  Y  N  N  37.028  12.798  35.118  ?  ?  ?  C63  2FJ   77  
2FJ  C64  C64  C   0  1  Y  N  N  36.750  13.760  34.148  ?  ?  ?  C64  2FJ   78  
2FJ  RU1  RU1  RU  2  0  N  N  N  40.887  26.565  27.198  ?  ?  ?  RU1  2FJ   79  
2FJ  RU2  RU2  RU  2  0  N  N  N  35.694  16.261  32.822  ?  ?  ?  RU2  2FJ   80  
2FJ  H1   H1   H   0  1  N  N  N  38.331  26.034  25.292  ?  ?  ?  H1   2FJ   81  
2FJ  H2   H2   H   0  1  N  N  N  36.466  24.397  25.446  ?  ?  ?  H2   2FJ   82  
2FJ  H3   H3   H   0  1  N  N  N  36.661  22.417  26.981  ?  ?  ?  H3   2FJ   83  
2FJ  H4   H4   H   0  1  N  N  N  42.737  26.182  29.946  ?  ?  ?  H4   2FJ   84  
2FJ  H5   H5   H   0  1  N  N  N  43.061  24.324  31.491  ?  ?  ?  H5   2FJ   85  
2FJ  H6   H6   H   0  1  N  N  N  41.684  22.319  31.332  ?  ?  ?  H6   2FJ   86  
2FJ  H7   H7   H   0  1  N  N  N  39.051  28.892  25.920  ?  ?  ?  H7   2FJ   87  
2FJ  H8   H8   H   0  1  N  N  N  38.853  30.094  23.780  ?  ?  ?  H8   2FJ   88  
2FJ  H9   H9   H   0  1  N  N  N  40.767  29.874  22.138  ?  ?  ?  H9   2FJ   89  
2FJ  H10  H10  H   0  1  N  N  N  42.337  27.907  22.446  ?  ?  ?  H10  2FJ   90  
2FJ  H12  H12  H   0  1  N  N  N  44.746  23.411  25.772  ?  ?  ?  H12  2FJ   91  
2FJ  H13  H13  H   0  1  N  N  N  45.009  24.296  23.533  ?  ?  ?  H13  2FJ   92  
2FJ  H14  H14  H   0  1  N  N  N  43.779  26.401  22.935  ?  ?  ?  H14  2FJ   93  
2FJ  H15  H15  H   0  1  N  N  N  43.954  27.282  26.816  ?  ?  ?  H15  2FJ   94  
2FJ  H16  H16  H   0  1  N  N  N  45.392  29.063  27.665  ?  ?  ?  H16  2FJ   95  
2FJ  H17  H17  H   0  1  N  N  N  44.433  31.126  28.757  ?  ?  ?  H17  2FJ   96  
2FJ  H18  H18  H   0  1  N  N  N  42.016  31.000  29.429  ?  ?  ?  H18  2FJ   97  
2FJ  H19  H19  H   0  1  N  N  N  37.808  26.699  28.330  ?  ?  ?  H19  2FJ   98  
2FJ  H20  H20  H   0  1  N  N  N  36.453  28.438  29.533  ?  ?  ?  H20  2FJ   99  
2FJ  H21  H21  H   0  1  N  N  N  37.723  30.199  30.783  ?  ?  ?  H21  2FJ  100  
2FJ  H22  H22  H   0  1  N  N  N  40.001  30.771  30.017  ?  ?  ?  H22  2FJ  101  
2FJ  H23  H23  H   0  1  N  N  N  33.622  16.643  30.392  ?  ?  ?  H23  2FJ  102  
2FJ  H24  H24  H   0  1  N  N  N  33.678  18.082  28.384  ?  ?  ?  H24  2FJ  103  
2FJ  H25  H25  H   0  1  N  N  N  35.257  19.960  28.294  ?  ?  ?  H25  2FJ  104  
2FJ  H26  H26  H   0  1  N  N  N  38.442  16.571  34.613  ?  ?  ?  H26  2FJ  105  
2FJ  H27  H27  H   0  1  N  N  N  40.394  18.027  34.295  ?  ?  ?  H27  2FJ  106  
2FJ  H28  H28  H   0  1  N  N  N  40.500  19.756  32.494  ?  ?  ?  H28  2FJ  107  
2FJ  H29  H29  H   0  1  N  N  N  33.935  13.771  31.705  ?  ?  ?  H29  2FJ  108  
2FJ  H30  H30  H   0  1  N  N  N  31.557  13.042  32.012  ?  ?  ?  H30  2FJ  109  
2FJ  H31  H31  H   0  1  N  N  N  29.979  14.659  33.083  ?  ?  ?  H31  2FJ  110  
2FJ  H32  H32  H   0  1  N  N  N  30.686  17.038  33.539  ?  ?  ?  H32  2FJ  111  
2FJ  H33  H33  H   0  1  N  N  N  36.373  18.875  34.748  ?  ?  ?  H33  2FJ  112  
2FJ  H34  H34  H   0  1  N  N  N  35.044  20.747  35.442  ?  ?  ?  H34  2FJ  113  
2FJ  H35  H35  H   0  1  N  N  N  32.567  20.611  35.393  ?  ?  ?  H35  2FJ  114  
2FJ  H36  H36  H   0  1  N  N  N  31.569  18.770  34.020  ?  ?  ?  H36  2FJ  115  
2FJ  H37  H37  H   0  1  N  N  N  36.326  15.203  29.856  ?  ?  ?  H37  2FJ  116  
2FJ  H38  H38  H   0  1  N  N  N  37.404  13.214  28.879  ?  ?  ?  H38  2FJ  117  
2FJ  H39  H39  H   0  1  N  N  N  37.968  11.351  30.316  ?  ?  ?  H39  2FJ  118  
2FJ  H40  H40  H   0  1  N  N  N  37.756  11.466  32.775  ?  ?  ?  H40  2FJ  119  
2FJ  H41  H41  H   0  1  N  N  N  35.633  16.231  35.980  ?  ?  ?  H41  2FJ  120  
2FJ  H42  H42  H   0  1  N  N  N  35.898  14.580  37.764  ?  ?  ?  H42  2FJ  121  
2FJ  H43  H43  H   0  1  N  N  N  36.903  12.337  37.224  ?  ?  ?  H43  2FJ  122  
2FJ  H44  H44  H   0  1  N  N  N  37.473  11.854  34.840  ?  ?  ?  H44  2FJ  123  
2FJ  H11  H11  H   0  1  N  N  N  43.144  24.406  27.340  ?  ?  ?  H11  2FJ  124  
#   #
loop_
_chem_comp_bond.comp_id
_chem_comp_bond.atom_id_1
_chem_comp_bond.atom_id_2
_chem_comp_bond.value_order
_chem_comp_bond.pdbx_aromatic_flag
_chem_comp_bond.pdbx_stereo_config
_chem_comp_bond.pdbx_ordinal
2FJ  C15  C16  DOUB  Y  N    1  
2FJ  C15  C14  SING  Y  N    2  
2FJ  C16  C17  SING  Y  N    3  
2FJ  C21  C20  DOUB  Y  N    4  
2FJ  C21  C22  SING  Y  N    5  
2FJ  C14  C13  DOUB  Y  N    6  
2FJ  C20  C19  SING  Y  N    7  
2FJ  C17  C22  SING  N  N    8  
2FJ  C17  N3   DOUB  Y  N    9  
2FJ  C22  N4   DOUB  Y  N   10  
2FJ  C13  N3   SING  Y  N   11  
2FJ  C19  C18  DOUB  Y  N   12  
2FJ  N4   C18  SING  Y  N   13  
2FJ  C1   C2   DOUB  Y  N   14  
2FJ  C1   N1   SING  Y  N   15  
2FJ  C2   C3   SING  Y  N   16  
2FJ  N1   C5   DOUB  Y  N   17  
2FJ  C3   C4   DOUB  Y  N   18  
2FJ  C23  N5   DOUB  Y  N   19  
2FJ  C23  C24  SING  Y  N   20  
2FJ  C5   C4   SING  Y  N   21  
2FJ  C5   C11  SING  Y  N   22  
2FJ  N5   C27  SING  Y  N   23  
2FJ  C4   C6   SING  Y  N   24  
2FJ  C24  C25  DOUB  Y  N   25  
2FJ  N6   C28  DOUB  Y  N   26  
2FJ  N6   C32  SING  Y  N   27  
2FJ  C27  C32  SING  N  N   28  
2FJ  C27  C26  DOUB  Y  N   29  
2FJ  C25  C26  SING  Y  N   30  
2FJ  C28  C29  SING  Y  N   31  
2FJ  N8   C6   DOUB  Y  N   32  
2FJ  N8   C38  SING  Y  N   33  
2FJ  C11  N2   SING  Y  N   34  
2FJ  C11  C10  DOUB  Y  N   35  
2FJ  C6   C12  SING  Y  N   36  
2FJ  C32  C31  DOUB  Y  N   37  
2FJ  N2   C7   DOUB  Y  N   38  
2FJ  C35  C34  DOUB  Y  N   39  
2FJ  C35  C36  SING  Y  N   40  
2FJ  C34  C33  SING  Y  N   41  
2FJ  C29  C30  DOUB  Y  N   42  
2FJ  C38  C36  DOUB  Y  N   43  
2FJ  C38  C44  SING  Y  N   44  
2FJ  C31  C30  SING  Y  N   45  
2FJ  C10  C12  SING  Y  N   46  
2FJ  C10  C9   SING  Y  N   47  
2FJ  C12  N10  DOUB  Y  N   48  
2FJ  C36  C37  SING  Y  N   49  
2FJ  C7   C8   SING  Y  N   50  
2FJ  C56  C55  DOUB  Y  N   51  
2FJ  C56  C57  SING  Y  N   52  
2FJ  C33  N7   DOUB  Y  N   53  
2FJ  C55  N13  SING  Y  N   54  
2FJ  C44  N10  SING  Y  N   55  
2FJ  C44  C42  DOUB  Y  N   56  
2FJ  C9   C8   DOUB  Y  N   57  
2FJ  C57  C58  DOUB  Y  N   58  
2FJ  C37  N7   SING  Y  N   59  
2FJ  C37  C43  DOUB  Y  N   60  
2FJ  C42  C43  SING  Y  N   61  
2FJ  C42  C41  SING  Y  N   62  
2FJ  C43  N9   SING  Y  N   63  
2FJ  N13  C59  DOUB  Y  N   64  
2FJ  C58  C59  SING  Y  N   65  
2FJ  C45  C46  DOUB  Y  N   66  
2FJ  C45  N11  SING  Y  N   67  
2FJ  C46  C47  SING  Y  N   68  
2FJ  C41  C40  DOUB  Y  N   69  
2FJ  C59  C64  SING  N  N   70  
2FJ  N11  C49  DOUB  Y  N   71  
2FJ  N9   C39  DOUB  Y  N   72  
2FJ  C47  C48  DOUB  Y  N   73  
2FJ  C49  C48  SING  Y  N   74  
2FJ  C49  C54  SING  N  N   75  
2FJ  C40  C39  SING  Y  N   76  
2FJ  C54  N12  DOUB  Y  N   77  
2FJ  C54  C53  SING  Y  N   78  
2FJ  N12  C50  SING  Y  N   79  
2FJ  C64  N14  DOUB  Y  N   80  
2FJ  C64  C63  SING  Y  N   81  
2FJ  C53  C52  DOUB  Y  N   82  
2FJ  N14  C60  SING  Y  N   83  
2FJ  C50  C51  DOUB  Y  N   84  
2FJ  C52  C51  SING  Y  N   85  
2FJ  C63  C62  DOUB  Y  N   86  
2FJ  C60  C61  DOUB  Y  N   87  
2FJ  C62  C61  SING  Y  N   88  
2FJ  N7   RU2  SING  N  N   89  
2FJ  N1   RU1  SING  N  N   90  
2FJ  RU1  N5   SING  N  N   91  
2FJ  RU1  N4   SING  N  N   92  
2FJ  RU2  N12  SING  N  N   93  
2FJ  RU2  N13  SING  N  N   94  
2FJ  C1   H1   SING  N  N   95  
2FJ  C2   H2   SING  N  N   96  
2FJ  C3   H3   SING  N  N   97  
2FJ  C7   H4   SING  N  N   98  
2FJ  C8   H5   SING  N  N   99  
2FJ  C9   H6   SING  N  N  100  
2FJ  C13  H7   SING  N  N  101  
2FJ  C14  H8   SING  N  N  102  
2FJ  C15  H9   SING  N  N  103  
2FJ  C16  H10  SING  N  N  104  
2FJ  C19  H12  SING  N  N  105  
2FJ  C20  H13  SING  N  N  106  
2FJ  C21  H14  SING  N  N  107  
2FJ  C23  H15  SING  N  N  108  
2FJ  C24  H16  SING  N  N  109  
2FJ  C25  H17  SING  N  N  110  
2FJ  C26  H18  SING  N  N  111  
2FJ  C28  H19  SING  N  N  112  
2FJ  C29  H20  SING  N  N  113  
2FJ  C30  H21  SING  N  N  114  
2FJ  C31  H22  SING  N  N  115  
2FJ  C33  H23  SING  N  N  116  
2FJ  C34  H24  SING  N  N  117  
2FJ  C35  H25  SING  N  N  118  
2FJ  C39  H26  SING  N  N  119  
2FJ  C40  H27  SING  N  N  120  
2FJ  C41  H28  SING  N  N  121  
2FJ  C45  H29  SING  N  N  122  
2FJ  C46  H30  SING  N  N  123  
2FJ  C47  H31  SING  N  N  124  
2FJ  C48  H32  SING  N  N  125  
2FJ  C50  H33  SING  N  N  126  
2FJ  C51  H34  SING  N  N  127  
2FJ  C52  H35  SING  N  N  128  
2FJ  C53  H36  SING  N  N  129  
2FJ  C55  H37  SING  N  N  130  
2FJ  C56  H38  SING  N  N  131  
2FJ  C57  H39  SING  N  N  132  
2FJ  C58  H40  SING  N  N  133  
2FJ  C60  H41  SING  N  N  134  
2FJ  C61  H42  SING  N  N  135  
2FJ  C62  H43  SING  N  N  136  
2FJ  C63  H44  SING  N  N  137  
2FJ  RU2  N9   SING  N  N  138  
2FJ  RU2  N11  SING  N  N  139  
2FJ  RU2  N14  SING  N  N  140  
2FJ  RU1  N3   SING  N  N  141  
2FJ  RU1  N2   SING  N  N  142  
2FJ  RU1  N6   SING  N  N  143  
2FJ  C18  H11  SING  N  N  144  
#   #
loop_
_pdbx_chem_comp_descriptor.comp_id
_pdbx_chem_comp_descriptor.type
_pdbx_chem_comp_descriptor.program
_pdbx_chem_comp_descriptor.program_version
_pdbx_chem_comp_descriptor.descriptor
2FJ  SMILES            ACDLabs               12.01  "n1c%13c(nc4c1c2cccn%11c2c3n(cccc34)[Ru+2]7%10%11(n5ccccc5c6ccccn67)n8ccccc8c9ccccn9%10)c%12cccn%21c%12c%14c%13cccn%14[Ru+2]%17%20%21(n%15ccccc%15c%16ccccn%16%17)n%18ccccc%18c%19ccccn%19%20"  
2FJ  InChI             InChI                 1.03   "InChI=1S/C24H12N6.4C10H8N2.2Ru/c1-5-13-17(25-9-1)18-14(6-2-10-26-18)22-21(13)29-23-15-7-3-11-27-19(15)20-16(24(23)30-22)8-4-12-28-20;4*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;/h1-12H;4*1-8H;;/q;;;;;2*+2"  
2FJ  InChIKey          InChI                 1.03   CUPZTUKKQZECGK-UHFFFAOYSA-N  
2FJ  SMILES_CANONICAL  CACTVS                3.385  "[Ru++]|1|2|3(|n4ccccc4c5ccccn|15)(|n6ccccc6c7ccccn|27)|n8cccc9c8c%10n|3cccc%10c%11nc%12c%13cccn%14|[Ru++]|%15|%16(|n%17ccccc%17c%18ccccn|%15%18)(|n%19ccccc%19c%20ccccn|%16%20)|n%21cccc(c%21c%13%14)c%12nc9%11"  
2FJ  SMILES            CACTVS                3.385  "[Ru++]|1|2|3(|n4ccccc4c5ccccn|15)(|n6ccccc6c7ccccn|27)|n8cccc9c8c%10n|3cccc%10c%11nc%12c%13cccn%14|[Ru++]|%15|%16(|n%17ccccc%17c%18ccccn|%15%18)(|n%19ccccc%19c%20ccccn|%16%20)|n%21cccc(c%21c%13%14)c%12nc9%11"  
2FJ  SMILES_CANONICAL  "OpenEye OEToolkits"  1.7.6  "C1=CC=[N]2C(=C1)C3=CC=CC=[N]3[Ru+2]245([N]6=C(C=CC=C6)C7=[N]4C=CC=C7)[N]8=C9C(=CC=C8)c1c(nc2c3c4c6c(c2n1)C=CC=[N]6[Ru+2]12([N]4=CC=C3)([N]3=C(C=CC=C3)C3=[N]1C=CC=C3)[N]1=C(C=CC=C1)C1=[N]2C=CC=C1)C1=C9[N]5=CC=C1"  
2FJ  SMILES            "OpenEye OEToolkits"  1.7.6  "C1=CC=[N]2C(=C1)C3=CC=CC=[N]3[Ru+2]245([N]6=C(C=CC=C6)C7=[N]4C=CC=C7)[N]8=C9C(=CC=C8)c1c(nc2c3c4c6c(c2n1)C=CC=[N]6[Ru+2]12([N]4=CC=C3)([N]3=C(C=CC=C3)C3=[N]1C=CC=C3)[N]1=C(C=CC=C1)C1=[N]2C=CC=C1)C1=C9[N]5=CC=C1"  
#
_pdbx_chem_comp_identifier.comp_id          2FJ
_pdbx_chem_comp_identifier.type             "SYSTEMATIC NAME"
_pdbx_chem_comp_identifier.program          ACDLabs
_pdbx_chem_comp_identifier.program_version  12.01
_pdbx_chem_comp_identifier.identifier       "tetrakis(2,2'-bipyridine-kappa~2~N~1~,N~1'~)(mu-tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]phenazine-1kappa~2~N~4~,N~5~:2kappa~2~N~13~,N~14~)diruthenium(4+)"
#   #
loop_
_pdbx_chem_comp_audit.comp_id
_pdbx_chem_comp_audit.action_type
_pdbx_chem_comp_audit.date
_pdbx_chem_comp_audit.processing_site
2FJ  "Create component"    2013-10-08  RCSB  
2FJ  "Initial release"     2013-10-16  RCSB  
2FJ  "Other modification"  2013-10-25  RCSB  
##
